WooCommerce does not currently have a option to sync directly with TrustFile.
WooCommerce's pre-built reporting is limited. The information for their reporting is found here.
To import transactions into TrustFile a .csv file is needed which includes Date, Price, Tax, and Shipping Address (including zip code). As mentioned on the WooCommerce site,
"The only columns and categories available are those shown. If you require a different or additional one, then it would be a customization requiring custom code or a plugin to add that feature/functionality."
If the report that is available via export from the Taxes tab does not include the required information, additional columns would need to be added.